Is this only worm poop and nothing else?

Yes, but so much more. Worm castings are covered in a calcium carbonate slime that, along with a large variety of bacteria, inhabit the worm's gut. As worms 'munch' their way through the soil, their deposits contain 10 times more potassium, 5 times more nitrogen, 7 times more phosphorus, 3 times more magnesium, and 1.5 more calcium and humus than the preexisting soil (in a form plants can easily utilize). Worm castings also contain high amounts of humic acid.

Can this be used as potting soil?

Typically it's used as the organic matter in potting soil. I make my own. My mix is 60% coco coir, 20% perlite and 20% worm castings.

How many pounds would i need to mix 20 5 gallon buckets for my container garden. 20 buckets is just under 14 cubic ft.

I'll tell you what I mix I mix one bag of the worm castings to one bag of potting soil in one brick of Coco coir with two bags perlite mixed all together I hope this helps one bag fills up about 3/4 of a 5 gallon bucket

Brand	Wiggle Worm
Item Weight	4.5 Pounds
Item Form	Granules
Liquid Volume	260 Cubic Inches
Specific Uses For Product	organic
Global Trade Identification Number	00090147439801
Manufacturer	UNCO INDUSTRIES,INC
Number of Items	1
UPC	795062603442 090147439801 355111055747 355111056959 355111057413
Net Quantity	2129.29 millilitre
Item model number	602
Product Dimensions	25.4 x 17.78 x 6.35 cm; 2.04 kg
ASIN	B000ZOEOEY

Unco Industries Wiggle Worm Organic Earthworm Castings Fertilizer, 4.5-Pound.

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