Would this work with a karcher fc5 hard floor cleaner?

I would expect it would be fine. We use it with a Vax hard floor cleaner and it works well a cleaning agent and leaves a pleasant fragrance on our room.

Can this be used on marble tile floors?

I use it on my porcelain floor tiles. As long as the marble is sealed it should be fine

Can I use this in a spray mop

i dont see why not , i use it as a pre-cleaner before i mop by spraying it on the floor then scrubbing it ,works really well

Has anyone tried that solution with a robot Ile irobot, roborock etc . Does it work well?

I don't own that machine but I have a Bissett floor washer and its fine in that so I'm guessing it would be ok in your machine although I wouldn't risk it if it was still under guarantee as it using a non proprietary product could invalidate the warranty

Package Dimensions	34.79 x 22.5 x 13.6 cm; 5 kg
Manufacturer reference	DB-000879
Volume	5 Litres
Units	5000.0 millilitre(s)
Brand	Dirtbusters
Format	Liquid
Manufacturer	Dirtbusters
Country of origin	United Kingdom

Dirtbusters Multi Floor Solution (5L), Multi Surface Floor Cleaner Liquid With Deodoriser For Hard Floor Cleaning Machines

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