Is there an app available that allows one to automatically backup photos and videos from a mobile device to the home network?

As far as I know, it is not possible. Access the fotos from your phone is possible via Synology Photos

Can I use 2-4TB SSD and use JBOD to get 8 TB storage?

I would say no. Using 2 4TB drives will only give you 4TB storage as one of the two drives is a mirror of the first one for fail-over. This is the purpose of NAS drive system. Synology website will explain the configurations in more detail. There are several excellent YouTube videos online to get more detailed information.

ASIN	B0BRNBVTJK
Best Sellers Rank	#15,201 in Computers ( See Top 100 in Computers ) #3 in Computer Servers
Brand	Synology
Color	Black
Colour	Black
Compatible Devices	Server
Compatible devices	Server
Customer Reviews	4.6 out of 5 stars 489 Reviews
EU Spare Part Availability Duration	2 Years
Enclosure Material	Metal
Is Assembly Required	Yes
Item Dimensions D x W x H	23.2D x 10.8W x 16.5H centimeters
Item Weight	1280 Grams
Manufacturer	Synology
Material	Metal
Mounting Type	Tabletop
Product dimensions	23.2D x 10.8W x 16.5H centimeters
Size	large
UPC	846504004775
Unit Count	1 Piece

Synology 2-Bay DS223 Quad Core CPU NAS Kit with 2GB Memory for Middle Light Users - Domestic Authorized Dealer Compatible Phone Support DiskStation

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